Theoretical and experimental design of Pt-Co(OH)_2 electrocatalyst for efficient HER performance in alkaline solution

Design efficient electrocatalysts become significant for the hydrogen evolution reaction (HER) in alkaline solution.Here,the HER performance on Pt-Co(OH)2 has been investigated by using DFT calculations.Compared with pure Pt,the Pt-Co(OH)2 shows excellent hydrogen binding energy (-0.29 eV) and hydrogen adsorption free energy (0.02 eV).More strikingly,the water dissociation process on Pt-Co(OH)2 is an exothermic reaction while that of Pt is an endothermic reaction,demonstrating that the Pt-Co(OH)_2 is an excellent catalyst for HER in alkaline medium.Then the two-step electrodepositions was used to fabricate Pt-Co(OH)2 on the carbon paper (CP).The Pt-Co(OH)_2/CP shows the lowest overpotential of only 37.6 mV at a current density of 10 mA cm~(-2) in 0.1M KOH,the smallest Tafel slope of58 mV dec~(-1) and the good stability for 20000s without obvious degradation.     

高炉铸铁冷却壁结构优化

采用正交试验和数值模拟方法对高炉炉身下部冷却壁主要结构参数进行优化,对优化前后的冷却壁温度场进行计算。结果表明,冷却壁热面最高温度的影响因素中影响程度从大到小依次为:水管直径、水管间距、水管中心线距冷却壁热面距离、壁体厚度,其中水管直径、水管间距和水管中心线距冷却壁热面距离为显著因素;最优冷却壁结构参数组合为:水管直径60mm、水管间距180mm、水管中心线距冷却壁热面距离120mm、壁体厚度220mm,优化后的冷却壁较优化前的冷却壁冷却性能有较大幅度的改善。     

开洞集装箱房屋结构纵向刚度分析

针对目前广泛使用的集装箱房屋,研究了开洞集装箱在外荷载作用下的纵向刚度.首先,利用蒙皮理论对其进行了力学分析,初步得出了开洞箱体刚度的计算方法,并通过算例阐述了具体的计算过程.然后,利用非线性有限元软件ABAQUS对其建立了有限元模型,并进行了基于开洞面积和洞口高长比的参数分析,得出了各参数对开洞箱体刚度的影响规律,并给出了相应的设计建议.最后,进行了5种开洞箱体刚度的试验研究,并将理论分析和有限元模拟的结果与试验数据进行了对比验证,吻合良好.本研究不仅可为目前广泛使用的集装箱房屋提供设计和施工参考,更可为相应的规范编制提供借鉴.     

长计数器的效率刻度及其应用

为了准确测定241Am-Be 中子源的强度,研制了一套长计数器测量系统,并利用四川大学2.5MV质子静电加速器产生的单能中子在多个中子能点对其探测效率进行刻度,在刻度过程中中子注量由金活化法确定,并采用挡锥法扣除大厅散射中子本底的贡献.结果表明我们研制的长计数器在所刻度的中子能区范围内具有很好的坪特性.用该长计数器测量系统测得241Am-Be 源的强度为7.188×105/s ,不确定度为3.5%.     

Tb~(3+)/Ce~(3+)掺杂硼酸盐玻璃的发光性能

采用高温熔融冷却法制备了Tb3+,Ce3+掺杂和Tb3+/Ce3+共掺硼酸盐玻璃,并利用荧光光谱研究了其发光性能。结果表明:在紫外光激发下,Tb3+掺杂玻璃最强发射峰位于545 nm;Ce3+掺杂玻璃的发射光谱是峰值位于387 nm附近的不对称宽带;Tb3+/Ce3+共掺玻璃的发射光谱是由380 nm附近的不对称宽带和491,545,588,623 nm附近的4个发射峰组成;在Tb3+/Ce3+共掺玻璃中,Ce3+是Tb3+的高效敏化剂,Tb3+的发射强度是Tb3+掺杂玻璃的8倍以上。     

船舶系统研制知识工程信息化平台建设

 船舶系统研制是一项典型的知识密集型的复杂工作，结合知识工程的具体实践，分析了知识工程体系的理论模型、建设内容和原则，探讨了知识工程信息化平台的构建，并展望了未来知识工程信息化的建设。应用本方法开展知识工程体系建设，可实现企业知识的有效获取和管理，促进知识与研发流程的关联应用，使得知识真正成为支撑企业发展的智力资产。     

白洋淀轮虫群落结构及富营养化评价

于2018年5月(春)、8月(夏)和10月(秋)对白洋淀26个采样点轮虫物种组成和群落结构进行了系统调查,测定了水温(WT)、溶解氧(DO)、pH值、水深(WD)、透明度(Tr)、总氮(TN)、总磷(TP)、叶绿素a(Chla)等环境因子,分析了轮虫群落参数与环境因子的关系,综合评价了白洋淀水体富营养化程度.共鉴定出轮虫21属61种,以耐污性种类为主,角突臂尾轮虫、萼花臂尾轮虫和小多肢轮虫为优势种.各采样点轮虫种数差异较大,最多为20种(聚龙淀),最少仅为6种(大麦淀).轮虫平均丰度和生物量呈现明显的季节变化,秋季最高(3 372 ind./L,0.90 mg/L),夏季其次(1 240 ind./L,0.88 mg/L),春季最低(210 ind./L,0.22 mg/L);轮虫最高丰度为6 930 ind./L(三角淀,秋季),最低仅为2 ind./L(平阳淀,夏季).Shannon-Wiener多样性指数(H')和Pielou均匀度指数(J)夏季最高(分别为2.30和0.86).经相关性分析发现,轮虫丰度与DO、WD、Chla、TP呈显著正相关,而与Tr显著负相关;轮虫种数与WD显著正相关,与WT显著负相关.与历史资料相比,白洋淀水质在一定程度有所好转,但仍处于富营养化状态.     

Effects of mechanical strain amplitude on the isothermal fatigue behavior of H13

Isothermal fatigue (IF) tests were performed on H13 tool steel subjected to three different mechanical strain amplitudes at a constant temperature to determine the effects of mechanical strain amplitude on the microstructure of the steel samples. The samples' extent of damage after IF tests was compared by observation of their cracks and calculation of their damage parameters. Optical microscopy (OM) and scanning electron microscopy (SEM) were used to observe the microstructure of the samples. Cracks were observed to initiate at the surface because the strains and stresses there were the largest during thermal cycling. Mechanical strain accelerated the damage and softening of the steel. A larger mechanical strain caused greater deformation of the steel, which made the precipitated carbides easier to gather and grow along the deformation direction, possibly resulting in softening of the material or the initiation of cracks.     

低成本纳米复合材料70％ CeO2·30％ NiO的合成及其催化性能的研究

分别选用水热,浸渍,柠檬酸络合燃烧,共沉淀方法合成了多种前驱体,再经过600 ℃煅烧处理4h,成功合成出纳米复合材料70％ CeO2·30％ NiO,对这些复合材料进行系统的XRD、BET、H2-TPR、O2-TPD表征和CO催化氧化性能测试.     

Pre-processing for time domain image formation in SS-BSAR system

A pre-processing procedure is designed for a space-surface bistatic synthetic aperture radar (SS-BSAR) system when a time domain image formation algorithm is employed. Three crucial technical issues relating to the procedure are fully discussed. Firstly, unlike image formation algorithms operating in the frequency domain, a time domain algorithm requires the accurate global navigation satellite system (GNSS) time and position. This paper proposes acquisition of this information using a time-and-spatial transfer with precise ephemeris and interpolation. Secondly, synchronization errors and compensation methods in SS-BSAR are analyzed. Finally, taking the non-ideal factors in the echo and the compatibility of image formation algorithms into account, a matched filter based on the minimum delay is constructed. Experimental result using real data suggest the pre-processing is functioning properly.